The Archie equation was the first empirical model built (1942) to estimate the water saturation in non conductive matrix rocks. It usually works well with clean clastic sandstones and carbonate rocks. Typical parameters for the Archie equation for consolidated sandstones are a=0.81 (tortuosity), m=1.7 (cementation exponent), and n=2.0 (saturation exponent). For carbonates, typical parameters are a=1.0; m=n=2.0.
When the rock matrix has some electrical conductivity, the resistivity is not only a function of the water resistivity R_{w} through their free dissolved ions, but also depends upon the matrix rock minerals beside the non conductive quartz and calcite matrix grains. The most common cases happen on clastic shaly rocks with important content of clay minerals.
In these shaly rocks the Archie law overestimates the water saturation. Many models consider the Shale Volume (Vshale or Volume of Shale) in the matrix to account for the excess of conductivity. The Simandoux equation (1963) is among the most used ones. It reduces mathematically to the Archie equation when n=2 and V_{sh}=0. Below are the expressions for the general Archie and Simandoux equations:
Other popular models that deal with shaly sands are the Fertl (1975) equation, and the 1971 PouponLeveaux (Indonesia) equation.
The Indonesia equation may work well with fresh formation water. The parameter R_{shale} (resistivity of shale) is usually taken from the resistivity reading of a nearby pure shale, assuming that the clay cements & silt, and the shale nature, are similar to those of the shaly sand.
The Fertl (1975) equation for shaly sands has the advantage that does not depend upon R_{shale}. It uses instead a reservoir dependent empirically adjusted 0.25 ≤ α ≤ 0.35 parameter α:
GeolOil has 19 builtin models for water saturation: Archie, Fertl, Simandoux, Schulumberger, PouponLeveaux (Indonesia), laminar shales, Dual Water, Juhasz, WaxmanSmits, Archie flushed zone ratio, irreducible low bound, irreducible Timur, saturation height through capillary pressure, and others.
All water saturation equations yield similar results to the Archie equation for moderately clean sands (see the aqua color clean sand zone in the picture below). However, the results differ in the case of shaly sand (see the pink color shaly sand zone), where the Archie law clearly overestimates the water saturation (too much water, so a pay zone could be easily missed if the Archie equation is the only model used).
The two following tables help to figure out how the water saturation SW and the hydrocarbon saturations SO and SG, move by trend increases or decreases on the electrical parameters a, m, n, Salinity, Rw, Rt, Vsh, Rsh, φ, α, and Cation Exchange Capacity Qv. As each parameter changes, the remaining ones are kept constant for sensibility comparisons.


The figure below compares the results of Archie, Simandoux, Indonesia, and Fertl models
The figure below shows the panel to compute water saturation using Archie, Fertl, & Simandoux equations
The figure below shows the calculation of water saturation using PouponLeveaux (Indonesia) & Dual Water Model algorithms